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Regional ¹⁸O-depletion of Neoproterozoic igneous rocks from Avalonia, Cape Breton Island and southern New Brunswick, Canada

J. Potter^,1, F.J. Longstaffe¹ and S.M. Barr²

¹ Department of Earth Sciences, The University of Western Ontario, London, Ontario, N6A 5B7, Canada
² Department of Geology, Acadia University, Wolfville, Nova Scotia, B4P 2R6, Canada

Neoproterozoic igneous rocks of the Avalonian Mira terrane, Cape Breton Island, and Caledonia terrane, southern New Brunswick, have experienced regional ¹⁸O-depletion. The majority of these rocks have ¹⁸O_WR values between –1 and +6, markedly different from igneous rocks of the inboard Ganderian terranes, which have normal-high ¹⁸O_WR values of +7 to +12. The ¹⁸O-depletion of these Avalonian terranes resulted from pervasive hydrothermal alteration. All of the igneous rocks contain classic propylitic alteration assemblages of turbid feldspar, chlorite, epidote, sericite, and calcite and host multiple generations of veins containing the same phases. The ¹⁸O values of the rock-forming minerals show strong disequilibrium with _qtz-fs ranging from +2.5 to +11.0 and _kfs-plg from –0.5 to +1.0. Such values are indicative of post-magmatic hydrothermal alteration. The hydrothermal alteration occurred at ca. 560–550 Ma during initial transcurrent rifting of Avalonia at the Gondwanan margin. The development of rift-wrench basins with associated bimodal volcanism allowed large volumes of hydrothermal fluids to penetrate and circulate within Mira and Caledonia terrane crust before its submergence in the early Cambrian (ca. 540–530 Ma). The hydrothermal fluids were predominantly meteoric, although the presence of a significant seawater component cannot be ruled out. The almost ubiquitous ¹⁸O-depletion exhibited by the Neoproterozoic rocks in these Avalonian terranes is absent in the associated Ganderian terranes, suggesting that Avalonia remained separate from Ganderia until at least the Cambrian-Ordovician. This ¹⁸O-depletion provides an additional geochemical tool for identification of Avalonian crust in other areas of the Appalachians and Europe.

Key Words: Avalonia • peri-Gondwanan • Neo-proterozoic • oxygen isotopes • granitoids

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